catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ2O,O′)neodymium(III)] [silver(I)-di-μ2-sulfido-tungsten(VI)-di-μ2-sulfido]]

catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ2O,O′)neodymium(III)] [silver(I)-di-μ2-sulfido-tungsten(VI)-di-μ2-sulfido]]

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In the title compound, {[Nd(NO3)2(C6H18N3OP)4][AgWS4]}n, the central Nd atom of the monovalent cation is coordinated by eight O atoms from two nitrate and four hexamethylphosphoramide ligands.The monovalent anion, click here {[WS4Ag]−}n, forms a polymeric chain in a distorted linear configuration with W—Ag—W and Ag—W—Ag angles of 163.81 (3) and 154.786 (12)°, respectively.

Thirteen C and three N atoms are disordered equally over two positions.One C atom is disordered over two positions with site occupancy factors of click here 0.6 and 0.4.